https://nova.newcastle.edu.au/vital/access/ /manager/Index en-au 5 https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:15861 Wed 11 Apr 2018 16:27:59 AEST ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:15868 Wed 11 Apr 2018 13:58:20 AEST ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:13193 2 (¹∆) whose formation is catalysed by the reactor surfaces, initiates the reaction at this low temperature. Quantum chemical computations of the reaction potential energy surfaces suggest low energy pathways to the observed initial products.]]> Wed 11 Apr 2018 13:51:15 AEST ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:13194 Wed 11 Apr 2018 13:35:06 AEST ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:15848 Wed 11 Apr 2018 13:07:52 AEST ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:15846 Wed 11 Apr 2018 12:14:38 AEST ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:13190 2). In this study, reaction rate constants are derived for H abstraction by H0₂ from the three distinct locations of H in ethylbenzene (primary, secondary and aromatic H, with H on the ortho carbon taken as an example of unreactive aromatic H) as well as for the addition of H at the four possible sites. Rate constants are provided in the simple Arrhenius form. The dominant channel at all temperatures is found to be H abstraction from the secondary C-H bonds of the ethyl chain, whereas abstractions from the primary C-H bonds also contribute significantly at higher temperatures. Reasonable agreement was obtained with the limited literature data. Addition at the four sites of the aromatic ring and abstraction of one of the C-H aromatic bonds are rather unimportant for all temperatures. The results presented herein should be useful in modeling the lower temperature oxidation of alkylbenzenes.]]> Wed 11 Apr 2018 11:55:59 AEST ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:15845 0.35) are preferred. However, the total efficiency decreases with increasing steam conversion. The negative effect on the efficiency can be offset by rising the temperature of AR. Furthermore, the optimum in the oxygen carrier circulation is found to be 40% excess stoichiometric value and higher than 95% is found to be unacceptable.]]> Wed 11 Apr 2018 11:15:12 AEST ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:13195 37Cl on the heat of formation of a series of polychlorinated phenols.]]> Wed 11 Apr 2018 10:19:32 AEST ]]>